Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02405c Click here for additional data file.

Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature.

Several ppm level gold-catalyzed reactions enabled by the ligand HandaPhos can be performed at room temperature in aqueous nanoreactors composed of the surfactant Nok. Variously substituted allenes undergo cycloisomerization leading to heterocyclic products in good yields. Likewise, cyclodehydration is also illustrated under similar conditions, as is an intermolecular variant, hydration of term...

Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc04907a Click here for additional data file.

Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles† †Electronic supplementary information (ESI) available. CCDC 1060973. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01772f Click here for additional data file. Click here for additional data file.

Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds† †Electronic supplementary information (ESI) available. CCDC 1028432. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03128h Click here for additional data file. Click here for additional data file.

Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V15Sb6}-type polyoxovanadates† †Electronic supplementary information (ESI) available: IR spectra, thermogravimetric analysis data, powder diffraction patterns, crystal morphology data, details of solubility studies, additional crystallographic and magnetochemical data and comment on the unassigned signals in the ESI mass spectra. CCDC 1432847–1432850. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc04571a Click here for additional data file. Click here for additional data file.